Pyridine meets difluorocarbene. Our paper on synthesis of difluoroalkylated hetarenes is finally online! Please check it out in @JOC_OL
#fluorine #carbene #heterocycles
bit.ly/3Bg0fx3
Dilman Lab retweeted
Just accepted Update by Alexander D. Dilman and co-authors: Generation of Alkyl #Radicals from #Thiols via #Zinc Thiolates: Application for the Synthesis of gem‐Difluorostyrenes onlinelibrary.wiley.com/doi/…
Dilman Lab retweeted
Just accepted Update by Alexander D. Dilman and co-authors: #Photoredox #Fluoroalkylation of #Hydrazones in Neutral and #Reductive Modes onlinelibrary.wiley.com/doi/…
Dilman Lab retweeted
Visible-light-promoted reversible sulfide/iodide exchange in fluoroalkyl sulfides enabled by electron donor-acceptor complex formation (van der Worp, Kosobokov, Dilman @DilmanLab) onlinelibrary.wiley.com/doi/…
Dilman Lab retweeted
After having thought about the dehydoxylative cross-coupling for years (since I was a postdoc in Baran Lab @BaranLabReads), we finally figured out an expedient method @J_A_C_S: pubs.acs.org/doi/10.1021/jac…
Dilman Lab retweeted
Using the Thiyl Radical for Aliphatic Hydrogen-Atom Transfer: Thiolation of Unactivated C-H Bonds by @DilmanLab onlinelibrary.wiley.com/doi/…
Dilman Lab retweeted
Boramidines are new motifs with potential in many areas. Finding small heterocycles that are stable to water and a wide range of solvents, yet have somehow eluded synthesis, is interesting. @A_Aspuru_Guzik @SeferosGroup pubs.acs.org/doi/10.1021/jac…
Dilman Lab retweeted
Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers @DilmanLab @BeilsteinInst: doi.org/10.3762/bjoc.16.126
Dilman Lab retweeted
ortho-Dialkylamino Arylboranes as Efficient Reagents for Difluorocarbene Trapping : pubs.rsc.org/en/content/arti…
Dilman Lab retweeted
Trapping of Difluorocarbene by Frustrated Lewis Pairs (Dilman) doi.wiley.com/10.1002/anie.2…
Thank you for highlighting our work.
Trapping of Difluorocarbene by Frustrated Lewis Pairs (@DilmanLab): onlinelibrary.wiley.com/doi/…
Dilman Lab retweeted
Acetylene trimerization reported by Berthelot and Zelinsky was finally unveiled. The mistery of self-promoted carbocatalytic synthesis of benzene. @AnanikovLab acspubs.co/Npvk30qhLwM
Dilman Lab retweeted
Double (vicinal) C-H functionalization of alcohols!
Check out this cool “reversed” radical/polar crossover mechanism @J_A_C_S by Allen, Raymond, & Ethan!
pubs.acs.org/doi/10.1021/jac…
Our latest paper "Visible-Light-Promoted Iododifluoromethylation of Alkenes via (Phosphonio)difluoromethyl Radical Cation" is now online
@JOC_OL
#visiblelight #catalysis #radicals
pubs.acs.org/doi/10.1021/acs…
Dilman Lab retweeted
Seeing double👀👀 after new year's revelry🎆? Then please check out our latest publication on dual Cr-photoredox catalysis to access 1,2-amino alcohols, just accepted in @J_A_C_S.
#chromium #photoredox #catalysis #aminoalcohols
pubs.acs.org/doi/10.1021/jac…
Dilman Lab retweeted
Ni(Fstb)3. An air-stable source of Ni(0). Thinking outside the (Glove)box. @LNattmann @rsaeb2 nature.com/articles/s41929-0…
Check out our new paper – now published in @ChemicalScience !
pubs.rsc.org/en/content/arti…
#photoredox #radical #fluorine
Dilman Lab retweeted
Photoredox Catalytic alpha-Alkoxypentafluorosulfanylation of alpha-methyl- and alpha-phenylstyrene using SF6 (Wagenknecht) doi.wiley.com/10.1002/anie.2…




























