VitovaGroup (@VitovaGroup) profile picture

VitovaGroup

@VitovaGroup
Joined August 2021
  • Tweets27
  • Following49
  • Followers49
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our new @J_A_C_S cover is out, photon modulated bond covalency of SmCNT2, @KITKarlsruhe @ACS4Authors #MyACSCover
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Featured on this week's covers: 'Photon-Modulated Bond Covalency of [Sm(II)(η9-C9H9)2]'. Read more 🔗 go.acs.org/alk
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our new paper just appeared in @J_A_C_S, with samarium cc-RIXS, VB-RIXS and LFDFT calculations: Photon-Modulated Bond Covalency of [Sm(II)(η9-C9H9)2] | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…. 4f-for-future @KITKarlsruhe
Photon-Modulated Bond Covalency of [Sm(II)(η9‑C9H9)2]

Photon-Modulated Bond Covalency of [Sm(II)(η9‑C9H9)2]

Abstract. Lanthanides are widely assumed not to form covalent bonds due to the localized nature of their 4f valence electrons. This work demonstrates that

pubs.acs.org
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Congrats! Bianca Schacherl has been selected for the KIT PhD award of 2023 for her PhD thesis "Advancing actinide high-energy resolution X-ray absorption / emission spectroscopic tools" @KITKarlsruhe
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Our first 2024 paper is out @InorgChem: Electronic Structure of Actinyls: Orbital Properties | Inorganic Chemistry pubs.acs.org/doi/10.1021/acs…
Electronic Structure of Actinyls: Orbital Properties

Electronic Structure of Actinyls: Orbital Properties

Abstract. A detailed analysis is presented for the covalent character of the orbitals in the actinyls: UO22+, NpO22+, and PuO22+. Both the initial, or grou

pubs.acs.org
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very happy to have Mustapha Laatiaoui today @KITKarlsruhe @LRC_Mainz
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very happy to have Stefan Minasian today @KITKarlsruhe
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Bianca ... last week in @KITKarlsruhe. We wish her all the best on her new adventure,
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very happy to have Ping Yang today @KITKarlsruhe
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VitovaGroup retweeted
AKRoesky (@AkRoesky) profile picture
AKRoesky@AkRoesky2 Aug 2023
Cyclocenes: A new class of sandwich compounds. Out now in @Nature ! We use unidirectional bending in divalent lanthanide multidecker species to assemble ring-shaped sandwich complexes with uniform metal-ligand coordination. nature.com/articles/s41586-0… @KITKarlsruhe @L1st1gerLurch
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Our latest ACS cover is out: Np(V) Retention at the Illite du Puy Surface surface paper! #MyACSCover pubs.acs.org/doi/10.1021/acs…
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VitovaGroup retweeted
AKRoesky (@AkRoesky) profile picture
AKRoesky@AkRoesky26 Jul 2023
Congratulations to @L1st1gerLurch and @realkingadi for their nice work about Mono-cyclononatetraenyl lanthanide complexes - now published in @ChemCommun pubs.rsc.org/en/content/arti…
Mono-cyclononatetraenyl lanthanide complexes†

Mono-cyclononatetraenyl lanthanide complexes†

The synthesis of the first half-sandwich complexes based on the cyclononatetraenyl (Cnt = C9H9−) ligand ([LnIII(η9-Cnt)(η3-BH4)2(thf)] (Ln = La, Ce)) is re

pubs.rsc.org
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Our latest Inorg. Chem. cover: Radioisotope power is key to exploring deep space and foreign worlds. Am-241 can be used in thermoelectric generators or heater units to provide reliable power to spacecraft and planetary rovers for decades.  pubs.acs.org/doi/10.1021/acs…
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#NewProfilePic
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Our latest issue is out! Read about the influence of bending in uranyl units, titanium(II) as a fuel atom, borylene hijinks, metal aromaticity, Xxx-Zzz peptidizationism, dinitrogen iron butterflies, and sundry other topics from across the Periodic Table pubs.acs.org/toc/inocaj/62/2…
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Synthesis, Characterization, and Stability of Two Americium Vanadates, AmVO3 and AmVO4 | Inorganic Chemistry pubs.acs.org/doi/full/10.102…
Synthesis, Characterization, and Stability of Two Americium Vanadates, AmVO3 and AmVO4

Synthesis, Characterization, and Stability of Two Americium Vanadates, AmVO3 and AmVO4

Abstract. In search for chemically stable americium compounds with high power densities for radioisotope sources for space applications, AmVO3 and AmVO4 we

pubs.acs.org
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The next #ChemSciCovers for issue 37 is from @MazzantiLab and @VitovaGroup The mechanism of Fe induced bond stability of uranyl(V) Image designed by Steliyana Lehchanska READ HERE: ow.ly/i86950KWx3H
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In their latest publication, @MazzantiLab and @VitovaGroup explore how the binding of Fe(II) to uranyl oxygen redistributes electron density towards equatorial ligands, increasing covalent character and therefore stabilising rare U(V) complexes. pubs.rsc.org/en/content/arti…
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Deep understanding of U(V) – ligand chemical bonding interactions and U(V) stability is achieved by high level computations and high energy resolution X-ray absorption and emission spectroscopy. @MazzantiLab @VitovaGroup #compchem #inorgchem #uranium pubs.rsc.org/en/content/arti…
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New research from @MazzantiLab @VitovaGroup. Understanding the stability of uranium complexes is key for understanding uranium migration in the environment. This work looks at the rare stability of U(V) due to Fe(II) and other ligands. pubs.rsc.org/en/content/arti…
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